岡山理科大学  
 Okayama University of Science
Last update September 2010
 
 
プロフィール
招待講演
業績
リンク
 
         
 
村橋 俊一 Shun-Ichi Murahashi
岡山理科大学 客員教授(常勤)
 
〒700-0005 岡山県岡山市北区理大町1-1
Tel 086-256-9513 Fax 086-256-4292
email murahashi  @ high.ous.ac.jp
URL http://www.ous.ac.jp/DAC/otera/murahashi/index.html
 
生年 1937年
略歴
1961年3月 大阪大学工学部応用化学科 卒業
1963年3月 大阪大学大学院工学研究科 修士課程修了
1963年4月 大阪大学 助手 基礎工学部
1967年5月 大阪大学工学博士 学位授与(守谷一郎教授)
1968-1970年 コロンビア大学 博士研究員(Ronald Breslow 教授)

1972年11月

大阪大学 助教授 基礎工学部
1979年4月 大阪大学 教授 基礎工学部
1992年 レンヌ大学 客員教授
1995-2000年 九州大学 教授(併任) 有機化学基礎研究センター
1997年4月 大阪大学大学院 教授 基礎工学研究科化学専攻(配置換え)
1997年5月 パリ・P.M. Curie大学 客員教授
1998-1999年 大阪大学 評議員
2000-2005年 日本学術会議 会員(18期、19期)
2001年3月 大阪大学 定年退官 大阪大学名誉教授
2001年4月 岡山理科大学 教授(客員)
2006年-現在 日本学術会議連携会員(20期、21期)
 
受賞
1970年 日本化学会進歩賞
1991年 日本学術振興会 NSERC Lectureship
1995年 日本化学会賞
1995年 Rennes大学名誉博士号 
1996年 MERCK-Schuchardt Lectureship 
2002年 フンボルト研究賞
2003年 Minakata-Avogadro講演賞 
2005年 有機合成化学特別賞 
2010年 日本学士院賞 
 
学会活動
1985-1997年 近畿化学協会 理事 
1989-1991年 日本化学会 理事
1991 有機合成化学協会 関西支部長
1991-1993年 有機合成化学協会 理事
1994年 日本化学会 副会長
1996-1998年 近畿化学協会 有機金属部会 部会長
1997-1999年 近畿化学協会 副会長
1999年 日本化学会 次期会長
2000年 化学技術戦略推進機構 理事
2000年 地球環境産業技術研究機構 評議員
2000年 日本化学会 会長
2001年- 財団法人高分子研究所 評議員
2002-2007年 日本学術振興会 創造機能化学第116委員会 委員長
2003-2007年 科学技術振興機構 化学技術振興審議会基礎研究部会委員
 
プロジェクト
1992-1995年 文部科学省科学研究費重点領域「反応性有機金属化合物」
1996-2001年 日本学術振興会未来開拓「環境調和型触媒プロセス」プロジェクトリーダー
 
学術誌編集委員及び委員長
1989-1991年 Chemistry Letters  編集委員
1992-2009 Synlett 国際名誉編集顧問
1994-1998年 Chemistry Letters  編集委員長
1998-2001年 Journal of Molecular Catalysis, A 編集委員 
1999-2002年 Green Chemistry 編集委員
2005年- Chemistry Letters  編集顧問
 
国際会議組織委員及び委員長
第7回有機合成指向有機金属化学国際会議(OMCOS-7:神戸):
 組織委員長(1993年5月)、組織委員(1991年より)
国際有機化学京都会議(IKCOC):組織委員(1979年[第1回]より)
均一系触媒国際会議(ISHC):組織委員(1998年より)
 
研究分野
有機合成指向有機金属化学
均一系触媒反応の開拓
グリーン触媒反応
生体触媒酸化反応
環境型遷移触媒反応 無塩プロセス
C-H 活性
講演

International Conference on Green & Sustainable Chemistry, Singapore, 2009.8.3-5.

11th International Symposium on Natural Products Chemistry, Karachi, Pakistan, 2008. 10.29-11.1.

15th National Conference on Organometallic Chemistry, Nanjing, China, 2008. 10.20-23.

9th International Symposium on Green Chemistry in China, Hefei, China, 2008.5.12-14.

Farewell Symposium Roger Sheldon A Journey in Green Chemistry, Delft, The Netherlands, 2007. 12. 6-7.

A*STAR-Noyori Forum Joint Symposium, Singapore, 2007. 5. 14-16.

International Symposium on Current Perspectives in Organic Chemistry, Kolkata, India, 2006. 12. 7-9.

The 21th Century COE International Symposium, Nagaoka, Japan, 2006. 9. 29-30.

The 4th Conference on Chemistry, Cairo, Egypt, 2006. 3. 5-8.

Organic Chemistry, Today and Tomorrow, Bangalore, India, 2006. 1. 4-7.

The 2005 Pacifichem Conference, Green Chemical Processes, Hawaii, USA, 2005. 12. 7.

The 15th International Symposium on Fine Chemistry and Functional Polymers, Shanghai, China, 2005. 10. 17-20.

The 7th World Congress on Recovery, Recycle, Re-integration, Chinese Academy of Science, Beijing, China, 2005. 9. 25-29.

The 1st International Symposium on Organic Electron Transfer Chemistry directed toward Organic Synthesis, Osaka, Japan, 2005. 3. 19-22.

2nd Symposium of High-tech Research Center Okayama University of Science, 2003. 11.24-25.

Minakata-Avogadro Lectureship, University of Rome, 2003. 4. 28-5.5. Rome, Bari, Bologna, Milano, Italy.

The lectureship to the memory of Ta-shue Chou, Taipei, Taiwan, 2003. 2. 22.

The 11th Japan−Korea Seminar on Organic Chemistry, Teju, Korea, 2002.11.7−10.
The 13th International Symposium on Homogeneous Catalysis, Tarragona, Spain, 2002.9.3−7.
India−Japan NOST Symposium on Organic Chemistry, Trivandrum, India, 2001.12.13−15.
First Japan−Australia Symposium on Organic Chemistry (JASOC-1), Melbourne, Australia, 2001.12.10−11.
First NIAF MeRinOS Joint Meeting on Fundamental and Applied Aspect of Synthesis, Belgium, 2001.9.28−10.2.
18th International Congress of Heterocyclic Chemistry, Yokohama, Japan, 2001.7.29−8.3.
Post OMCOS-XI Symposium, Thirty Years of The Cross-Coupling reaction, Kyoto, Japan, 2001.7.27−28.
11th IUPAC Symposium on Organometallic Chemistry directed towards Organic Synthesis, Taipei, Taiwan, 2001.7.22−26.
The 87th Annual Meeting of the Korean Chemical Society, Seoul, Korea, 2001.4.20.
The Breslow Symposium―Celebrating the 70th Birthday of Ronald Breslow, New York, USA, 2001.3.24.
2000 International Chemical Congress of Pacific Basin Societies (Pacifichem 2000), Honolulu, Hawaii, USA, 2000.12.14−19.
The 10th Japan−Korea Seminar on Organic Chemistry, Sendai, Japan, 2000.11.26−28.
2000 International Symposium on Organic Reactions (ISOR 2000), Kyoto, Japan, 2000.10.24.
Special Symposium Inaugurating the Herbert C. Brown Distinguished Professorship and the Annual Industrial Associates Meeting, West Lafyete, USA, 2000.9.28−30.
Congre´s de la Socie´te´ Francaise de Chimie, Rennes, France, 2000.9.18−22.
XIXth International Conference on Organometallic Chemistry (ICOMC), Shanghai, China, 2000.7.23−28.
Gratama Workshop 2000-Chemistry and Chemical Technology for a Sustainable Society, Osaka, Japan, 2000.4.21−25.

 
 

発表論文

 

S.-I. Murahashi, A. Fujii, Y. Inubushi and N. Komiya: Synthesis of 2-substituted quinones, vitamin K3, and vitamin K1 from p-cresol. BF3・OEt2-catalyzed methyl migration of 4-tert-butyldioxycyclohexadienones, Tetrahedron Letters, 51, 2339-2341 (2010).

H. Takaya, M. Ito, and S.-I. Murahashi: Rhenium-Catalyzed Addition of Carbonyl Compounds to the Carbon-Nytrogen Triple Bonds of Nitriles:α-C-H Activation of Carbonyl Compounds, J. Am.Chem. Soc.,131,10824-10825 (2009).

S.-I. Murahashi, T. Naota, and Y. Nakano: Ruthenium-Catalyzed Regioselective Reactions of Nitriles and 1,3−Dicarbonyl Compounds with Terminal Alkynes, Synlett, 3355-3360 (2009).

Y. Guo, X. Zhao, D. Zhang, S.-I. Murahashi: Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes:A Csp3---H Bond Activation a to the Trifluoromethyl Group, Angew. Chem. Int. Ed., 48, 2047-2949, (2009).

S.-I. Murahashi, T. Nakae, H. Terai, N. Komiya: Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Molecular Oxygen or Hydrogen Peroxide and Sodium Cyanide: sp3 C-H Bond Activation and Carbon-Carbon Bond Formation, J. Am. Chem. Soc., 130, 11005-11012 (2008).

T. Naota, A. Tanna, S. Kamuro, M. Hieda, K. Ogata, S.-I. Murahashi, H. Takaya: Switchable C- and N-Bound Isomers of Transition-Metal Cyanocarbanions: Synthesis and Interconversions of Cyclopentadienyl Ruthenium Complexes of Phenylsulfonylacetonitrile Anions, Chem. Eur. J., 14, 2482-2498(2008).

S.-I. Murahashi, and D. Zhang: Ruthenium Catalyzed Biomimetic Oxidation in Organic Synthesis Inspired by Cytochrome P-450, Chemical Society Reviews, 37, 1490-1501 (2008).

K. Suzuki, T. Watanabe, S.-I. Murahashi: Aerobic Oxidative Transformation of Primary Amines to Oximes Catalyzed by 1,1-Diphenyl-2-picrylhydrazyl (DPPH) and Tungstated Alumina, Angew. Chem. Int. Ed., 47, 2079-2081(2008).

S.-I. Murahashi, Y. Okano, H. Sato, T. Nakae, N. Komiya: Aerobic Ruthenium-Catalyzed Oxidative Transformation of Secondary Amines to Imines, Synlett, 1675-1678 (2007).

L. Provins, and S.-I. Murahashi: Oxidation of Olefins Catalyzed by New Binaphthyl-ruthenium(III) Complexes, Arkivoc, (x)107-120 (2007).

S.-I. Murahashi: Development of Ruthenium Catalyzed Oxidation Reactions Inspired by Cytochrome P-450, J. Synth. Org. Chem. Jpn., 65, 1, 2-13 (2007).

Y. Imada, H. Iida, S. Ono, Y. Masui, S.-I. Murahashi: Flavin-Catalyzed Oxidation of Amines and Sulfides with Molecular Oxygene: Biomimetic Green Oxidation, Chem. Asian. J. 1, 136-147 (2006).

Y. Imada, M. Nishida, K. Kutsuwa, S. I. Murahashi, T. Naota, Palladium-Catalyzed Asymmetric Amination of 2,3-Allyl Phosphates, Org. Lett. 7, 5837-5839(2005).

S.-I. Murahashi, S. Noji, T. Hirabayashi, N. Komiya, Manganese-Catalyzed Enantioselective Oxidation of C-H Bonds of Alkanes and Silyl Ethers to Optically Active Ketones, Tetrahedron Asymmetry 16, 3527-3535(2005).

S.-I. Murahashi, N. Komiya, H. Terai,  Ruthenium-Catalyzed Oxidative Cyanation of TertiaryAmines with Hydrogen Peroxide and Sodium Cyanide, Angew. Chem. Int. Ed. 44, 6931-6933(2005).

Y. Imada, H. Iida, S.-I. Murahashi, and T. Naota, An Aerobic Organocatalytic, and Chemoselective Method for Baeyer-Villiger Oxidation, Angew. Chem. Internal. Ed. 44, 1704-1706(2005).

S.-I. Murahashi, S. Noji, and N. Komiya, Catalytic Enantioselective Oxidation of Alkanes and Alkenes Using (Salen)Manganese Complexes Bearing a Chiral Binaphthyl Strapped Unit,  Adv. Synth. Catal. 346, 195-198(2004).

H. Terai, H. Takaya, and S.-I. Murahashi,. Iridium-Catalyzed Selective C-C Bond Cleavage of Nitriles and Ketones. Synlett 2185-2187(2004).

S.-I. Murahashi. S. Noji, T. Hirabayashi, and N. Komiya, Manganase-Catalyzed Oxidative Transformation of Silyl Ethers to Ketones: Enantioselective Synthesis of Optically Active β-and γ-Siloxylketones. Synlett. 1739-1742(2004).

Shun-Ichi Murahashi:  Transition-Metal-Based Lewis Acid, Base, and Ambiphilic Catalyst. Development of Non-salt Processes, J. Syn. Org. Chem. Jpn., 61, 425-435 (2003).

S.-I. Murahashi, N. Komiya, H. Terai, and T. Nakae, Aerobic Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Sodium Cyanide,  J. Am. Chem. Soc. 125, 15312-15313(2003).

Y. Imada, H. Iida, S. Ono, and S.- I. Murahashi, Flavin Catalyzed Oxidations of Sulfides and Amines with Molecular Oxygen, J. Am. Chem. Soc. 125, 2868-2869(2003).

H. Takaya, K. Yoshida, K. Isozaki, H. Terai, and S. - I. Murahashi, Transition-Metal-Based Lewis Acid and Base Ambiphilic Catalysts of Iridium Hydride Complexes: Multicomponent Synthesis of Glutarimides, Angew. Chem. Inter. Ed. 42, 3302-3304(2003).

S. - I. Murahashi, X. Zhou, and N. Komiya, Chlorinated Phthalocyanine Iron(II) Complex Catalyzed Oxidation of Alkanes and Alkenes with Molecular Oxygen in the Presence of Acetaldehyde,  Synlett 321-324(2003).

S.-I. Murahashi: Development of Biomimetic Catalytic Oxidation Reactions, Shokubai 44, 259-264 (2002).


S.-I. Murahashi, H. Takaya, and T. Naota: Ruthenium Catalysis in Organic Synthesis, Pure Appl. Chem. 74, 19−23 (2002).


T. Naota, A. Tanna, S. Kamuro, and S.-I. Murahashi: Mechanism of the Interconversions between C- and N-Bound Transition Metal a-Cyanocarbanions, J. Am. Chem. Soc. 124, 6842−6843 (2002).


S.-I. Murahashi, S. Ono, and Y. Imada: Asymmetric Baeyer−Villiger Reaction with Hydrogen Peroxide Catalyzed by a Novel Planar-Chiral Bisflavin, Angew. Chem. Int. Ed. 41, 2366−2368 (2002).


S.-I. Murahashi, Y. Imada, T. Kawakami, K. Harada, Y. Yonemushi, and N. Tomita: Enantioselective Addition of Ketene Silyl Acetals to Nitrones Catalyzed by Chiral Titanium Complexes. Synthesis of Optically Active b-Amino Acids, J. Am. Chem. Soc. 124, 2888−2889 (2002).


S.-I. Murahashi: Palladium-Catalyzed Cross-Coupling Reactions of Organic Halides with Grignard Reagents, Organolithium Compounds, and Heteroatom Nucleophiles, J. Organomet. Chem. 653, 27−33 (2002).


Y. Imada, K. Ueno, K. Kutsuwa, and S.-I. Murahashi: Palladium-Catalyzed Asymmetric Alkylation of Alka-2,3-dienyl Phosphates. Synthesis of Optically Active Allenes, Chem. Lett. 140−141 (2002).


T. Hottop, H.-J. Gutke, and S.-I. Murahashi: Synthesis of 4-Demethoxyadriamycinone Utilizing Ruthenium-Catalyzed Oxidation of Allyl Acetates, Tetrahedron Lett. 42, 3343−3346 (2001).


H. Takaya and S.-I. Murahashi: Activation of C―H Bonds a to Nitriles for Combinatorial Chemistry: Ruthenium-Catalyzed Aldol and Michael Reactions of Polymer-Supported Nitriles, Synlett 991−992 (2001).


S.-I. Murahashi, N. Komiya, Y. Hayashi, and T. Kumano: Copper Complexes for Catalytic, Aerobic Oxidation of Hydrocarbons, Pure & Appl. Chem. 73, 311−314 (2001).


H. Takaya, S. Kojima, and S.-I. Murahashi: Rhodium Complex-Catalyzed Reaction of Isonitriles with Carbonyl Compounds: Catalytic Synthesis of Pyrroles, Org. Lett. 3, 421−424 (2001).


T. Naota, A. Tannna, and S.-I. Murahashi: Carbon-Carbon Bond Forming Reactions of N-Bound Transition Metal a-Cyanocarbanions: A Mechanistic Probe for Catalytic Michael Reactions of Nitriles, Chem. Commun. 63−64 (2001).


N. Komiya, S. Noji, and S.-I. Murahashi: Ruthenium-catalysed Oxidation of Alkanes with Peracetic Acid in Trifluoroacetic Acid: Ruthenium as an Efficient Catalyst for the Oxidation of Unactivated C-H Bonds, Chem. Commun. 65−66 (2001).

S.-I. Murahashi, N. Komiya, Y. Oda, T. Kuwabara, and T. Naota: Ruthenium-Catalyzed Oxidation of Alkanes with tert-Butyl Hydroperoxide and Peracetic Acid, J. Org. Chem. 65, 9186−9193 (2000).


S.-I. Murahashi, A. Mitani, and K. Kitao: Ruthenium Catalyzed Glycine-Selective Oxidative Backbone Modification of Peptides, Tetrahedron Lett. 41, 10246−10249 (2000).


T. Kawakami, H. Ohtake, H. Arakawa, T. Okachi, Y. Imada, and S.-I. Murahashi: Asymmetric Synthesis of b-Amio Acids by Addition of Chiral Enolates to Nitrones via N-Acyloxyiminium Ions, Bull. Chem. Soc. Jpn. 73, 2423−2444 (2000).


S.-I. Murahashi, K. Take, T. Naota, and H. Takaya: Aldol and Michael Reactions of Nitriles Catalyzed by Cyclopentadienylruthenium Enolate Complexes, Synlett 1016−1018 (2000).


S.-I. Murahashi and H. Takaya: Low-Valent Ruthenium and Iridium Hydride Complexes as Alternatives to Lewis Acid and Base Catalysts, Acc. Chem. Res. 33, 225−233 (2000).


T. Naota, A. Tannna, and S.-I. Murahashi: Synthesis and Characterization of C- and N-Bound Isomers of Transition Metal a-Cyanocarbanions, J. Am. Chem. Soc. 122, 2960−2961 (2000).


S.-I. Murahashi, T. Tsuji, and S. Ito: Synthesis of Optically Active N-Hydroxylamines by Asymmetric Hydrogenation of Nitrones with Iridium Catalysts, Chem. Commun. 409−410 (2000).


S.-I. Murahashi, K. Kitao, and A. Mitani: Glycine-Selective Ruthenium Catalyzed Oxidative Modification of Short Peptides, Peptide Science 1999, 137−140 (2000).


S.-I. Murahashi, J. Sun, H. Kurosawa, and Y. Imada: Synthesis of Homochiral b-Sulfinyl Nitrones and Their Application for Enantioselective Synthesis of (+)-Euphococcinine, Heterocycles 52, 557−561 (2000).

 

著書・総説

 

村橋俊一: 私が化学を選んだ理由、化学だいすきクラブニュースレター、日本化学会化学教育協議会、3(2008.夏号).

S.-I. Muranashi, N. Komiya, Ruthenium-catalyzed Oxidation for Organic Synthesis, In Modern Oxidation Methods, 2nd Ed., Ed., J.-E. Backvall, Wiley-VCH, Weinheim, in press.

Shun-Ichi Murahashi: Palladium-Phosphine-Complex-Catalyzed Reaction of Organolithium Compounds and Alkenyl Halides: (Z)-β-[2-(N,N-dimethylamino)phenyl]styrene, In Thematic Collection Organic Synthesis, Ed., R. Danheiser, in press.

Shun-Ichi. Murahashi and Yasushi Imada:  Asymmetric Synthesis of Amines and Amino Acids from Amines, Asymmetric Synthesis-The Essentials, Eds., S. Braese, M. Christmann, Wiley-VCH, Weinheim, 40-44 (2007).

Shun-Ichi Murahashi and Changjia Zhao::Pentahydridobis(triisopropylphosphine)iridium(V) In Electronic Encyclopedia of Reagents for Organic Synthesis, Ed. L. A. Paquette, Wiley, New York, (2006).

Shun-Ichi Murahashi and Changjia Zhao: Dichlorotris(triphenylphosphine)ruthenium(II) In Electronic Encyclopedia of Reagents for Organic Synthesis, Ed. L. A. Paquette, Wiley, New York, (2006).

Shun-Ichi. Murahashi:  Transition Metal Catalyzed C-H Activation of Pronucleophile by α-Heteroatom Effect, In Handbook of CH Transformation, Ed. G. Dyker, Wiley-VCH, Weinheim,Vol.2, 319-328 (2005).

Shun-Ichi Murahashi:  Synthesis of Nitriles with Retention of the Cyano Group, In  Science of  Synthesis, Ed., Shun-Ichi Murahashi, Thieme, Stuttgart, Vol 19, 345-425 (2004).

Shun-Ichi Murahashi and Yasushi Imada:  Amine Oxidations, In Transition Metals for Organic Syntheis, Vol 2. Second Revised and Enlarged, Ed., M. Beller, C. Bolm, Wiley-VCH, Weinheim, 497-507 (2004).

Shun-Ichi Murahashi and Naruyoshi Komiya:  Ruthenium-Catalyzed Oxidation of Alkenes, Alcohols, Amines, beta-Lactams, Phenols, and Hydrocarbons, In Modern Oxidation Methods, Ed., J.-E. Backvall, Wiley-VCH, Weinheim, 165-191(2004).

Shun-Ichi Murahashi and Naruyoshi Komiya:  Oxidation Reactions, In Ruthenium in Organic Synthesis Ed., Shun-Ichi Murahashi, Wiley-VCH, Weinheim, 53-93 (2004).

S.-I. Murahashi and N. Komiya: Oxidation of Amines, Alcohols, and Related Compounds, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2881−2894 (2002).


T. Hosokawa and S.-I. Murahashi: Oxypalladation−Dehydropalladation Tandem and Related Reactions, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2169−2192 (2002).


T. Hosokawa and S.-I. Murahashi: Intermolecular Oxypalladation Not Accompanied by Dehydrogenation, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2161−2168 (2002).


T. Hosokawa and S.-I. Murahashi: Other Intramolecular Oxypalladation-Dehydropalladation Reactions, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2141−2159 (2002).


S.-I. Murahashi and Y. Imada: Palladium-Catalyzed Substitution Reactions of Nitrogen and Other Group 15 Atom Containing Allylic Derivatives, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 1817−1825 (2002).


S.-I. Murahashi: Recommendation for Green Chemistry, Kagaku to Kyoiku, 50, 426−429 (2002).


S.-I. Murahashi: Green Chemistry−Homogeneous Complex Catalysts, In Green Chemistry−Chemistry for Sustainable Society, Ed., by Makoto Misonou and S.-I. Murahashi, Kodansha, Tokyo, 99−111 (2001).


S.-I. Murahashi: Development of Transition Metal Catalyst as Lewis Acid or Base Substitutes, Organomet. News, 90−93 (2001).


S.-I. Murahashi: Green Chemistry and the Development of New Catalyst Therefor, Kagaku Kogyo, 51, 409−416 (2000).


S.-I. Murahashi: Exploitation of New Catalytic Reactions, Kagaku Kogyo, 51, 52−57 (2000).