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| 村橋 俊一 |
Shun-Ichi Murahashi |
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| 岡山理科大学 客員教授(常勤) |
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| 〒700-0005 岡山県岡山市北区理大町1-1 |
| Tel 086-256-9513 Fax 086-256-4292 |
| email |
murahashi |
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high.ous.ac.jp |
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| URL http://www.ous.ac.jp/DAC/otera/murahashi/index.html |
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| 生年 1937年 |
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| 略歴 |
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| 1963年3月 |
大阪大学大学院工学研究科 修士課程修了 |
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| 1967年5月 |
大阪大学工学博士 学位授与(守谷一郎教授) |
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| 1968-1970年 |
コロンビア大学 博士研究員(Ronald Breslow 教授) |
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| 1995-2000年 |
九州大学 教授(併任) 有機化学基礎研究センター |
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| 1997年4月 |
大阪大学大学院 教授 基礎工学研究科化学専攻(配置換え) |
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| 1997年5月 |
パリ・P.M. Curie大学 客員教授 |
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| 2000-2005年 |
日本学術会議 会員(18期、19期) |
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| 2001年3月 |
大阪大学 定年退官 大阪大学名誉教授 |
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| 2006年-現在 |
日本学術会議連携会員(20期、21期) |
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| 受賞 |
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| 1991年 |
日本学術振興会 NSERC Lectureship |
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| 1996年 |
MERCK-Schuchardt Lectureship |
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| 2003年 |
Minakata-Avogadro講演賞 |
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| 学会活動 |
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| 1996-1998年 |
近畿化学協会 有機金属部会 部会長 |
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| 2002-2007年 |
日本学術振興会 創造機能化学第116委員会 委員長 |
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| 2003-2007年 |
科学技術振興機構 化学技術振興審議会基礎研究部会委員 |
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| プロジェクト |
| 1992-1995年 |
文部科学省科学研究費重点領域「反応性有機金属化合物」 |
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| 1996-2001年 |
日本学術振興会未来開拓「環境調和型触媒プロセス」プロジェクトリーダー |
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| 学術誌編集委員及び委員長 |
| 1989-1991年 |
Chemistry Letters 編集委員 |
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| 1992-2009 |
Synlett 国際名誉編集顧問 |
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| 1994-1998年 |
Chemistry Letters 編集委員長 |
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| 1998-2001年 |
Journal of Molecular Catalysis, A 編集委員 |
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| 1999-2002年 |
Green Chemistry 編集委員 |
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| 2005年- |
Chemistry Letters 編集顧問 |
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| 国際会議組織委員及び委員長 |
| 第7回有機合成指向有機金属化学国際会議(OMCOS-7:神戸): |
| 組織委員長(1993年5月)、組織委員(1991年より) |
| 国際有機化学京都会議(IKCOC):組織委員(1979年[第1回]より) |
| 均一系触媒国際会議(ISHC):組織委員(1998年より) |
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| 研究分野 |
| 有機合成指向有機金属化学 |
| 均一系触媒反応の開拓 |
| グリーン触媒反応 |
| 生体触媒酸化反応 |
| 環境型遷移触媒反応 無塩プロセス |
| C-H 活性 |
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| 講演 |
International Conference on Green & Sustainable Chemistry, Singapore, 2009.8.3-5.
11th International Symposium on Natural Products Chemistry, Karachi, Pakistan, 2008. 10.29-11.1.
15th National Conference on Organometallic Chemistry, Nanjing, China, 2008. 10.20-23.
9th International Symposium on Green Chemistry in China, Hefei, China, 2008.5.12-14.
Farewell Symposium Roger Sheldon A Journey in Green Chemistry, Delft, The Netherlands, 2007. 12. 6-7.
A*STAR-Noyori Forum Joint Symposium, Singapore, 2007. 5. 14-16.
International Symposium on Current Perspectives in Organic Chemistry, Kolkata, India, 2006. 12. 7-9.
The 21th Century COE International Symposium, Nagaoka, Japan, 2006. 9. 29-30.
The 4th Conference on Chemistry, Cairo, Egypt, 2006. 3. 5-8.
Organic Chemistry, Today and Tomorrow, Bangalore, India, 2006. 1. 4-7.
The 2005 Pacifichem Conference, Green Chemical Processes, Hawaii, USA, 2005. 12. 7.
The 15th International Symposium on Fine Chemistry and Functional Polymers, Shanghai, China, 2005. 10. 17-20.
The 7th World Congress on Recovery, Recycle, Re-integration, Chinese Academy of Science, Beijing, China, 2005. 9. 25-29.
The 1st International Symposium on Organic Electron Transfer Chemistry directed toward Organic Synthesis, Osaka, Japan, 2005. 3. 19-22.
2nd Symposium of High-tech Research Center Okayama University of Science, 2003. 11.24-25.
Minakata-Avogadro Lectureship, University of Rome, 2003. 4. 28-5.5. Rome, Bari, Bologna, Milano, Italy.
The lectureship to the memory of Ta-shue Chou, Taipei, Taiwan, 2003. 2. 22.
The 11th Japan−Korea Seminar on Organic Chemistry, Teju, Korea, 2002.11.7−10.
The 13th International Symposium on Homogeneous Catalysis, Tarragona, Spain, 2002.9.3−7.
India−Japan NOST Symposium on Organic Chemistry, Trivandrum, India, 2001.12.13−15.
First Japan−Australia Symposium on Organic Chemistry (JASOC-1), Melbourne, Australia, 2001.12.10−11.
First NIAF MeRinOS Joint Meeting on Fundamental and Applied Aspect of Synthesis, Belgium, 2001.9.28−10.2.
18th International Congress of Heterocyclic Chemistry, Yokohama, Japan, 2001.7.29−8.3.
Post OMCOS-XI Symposium, Thirty Years of The Cross-Coupling reaction, Kyoto, Japan, 2001.7.27−28.
11th IUPAC Symposium on Organometallic Chemistry directed towards Organic Synthesis, Taipei, Taiwan, 2001.7.22−26.
The 87th Annual Meeting of the Korean Chemical Society, Seoul, Korea, 2001.4.20.
The Breslow Symposium―Celebrating the 70th Birthday of Ronald Breslow, New York, USA, 2001.3.24.
2000 International Chemical Congress of Pacific Basin Societies (Pacifichem 2000), Honolulu, Hawaii, USA, 2000.12.14−19.
The 10th Japan−Korea Seminar on Organic Chemistry, Sendai, Japan, 2000.11.26−28.
2000 International Symposium on Organic Reactions (ISOR 2000), Kyoto, Japan, 2000.10.24.
Special Symposium Inaugurating the Herbert C. Brown Distinguished Professorship and the Annual Industrial Associates Meeting, West Lafyete, USA, 2000.9.28−30.
Congre´s de la Socie´te´ Francaise de Chimie, Rennes, France, 2000.9.18−22.
XIXth International Conference on Organometallic Chemistry (ICOMC), Shanghai, China, 2000.7.23−28.
Gratama Workshop 2000-Chemistry and Chemical Technology for a Sustainable Society, Osaka, Japan, 2000.4.21−25. |
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発表論文 |
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S.-I. Murahashi, A. Fujii, Y. Inubushi and N. Komiya: Synthesis of 2-substituted quinones, vitamin K3, and vitamin K1 from p-cresol. BF3・OEt2-catalyzed methyl migration of 4-tert-butyldioxycyclohexadienones, Tetrahedron Letters, 51, 2339-2341 (2010).
H. Takaya, M. Ito, and S.-I. Murahashi: Rhenium-Catalyzed Addition of Carbonyl Compounds to the Carbon-Nytrogen Triple Bonds of Nitriles:α-C-H Activation of Carbonyl Compounds, J. Am.Chem. Soc.,131,10824-10825 (2009).
S.-I. Murahashi, T. Naota, and Y. Nakano: Ruthenium-Catalyzed Regioselective Reactions of Nitriles and 1,3−Dicarbonyl Compounds with Terminal Alkynes, Synlett, 3355-3360 (2009).
Y. Guo, X. Zhao, D. Zhang, S.-I. Murahashi: Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes:A Csp3---H Bond Activation a to the Trifluoromethyl Group, Angew. Chem. Int. Ed., 48, 2047-2949, (2009).
S.-I. Murahashi, T. Nakae, H. Terai, N. Komiya: Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Molecular Oxygen or Hydrogen Peroxide and Sodium Cyanide: sp3 C-H Bond Activation and Carbon-Carbon Bond Formation, J. Am. Chem. Soc., 130, 11005-11012 (2008).
T. Naota, A. Tanna, S. Kamuro, M. Hieda, K. Ogata, S.-I. Murahashi, H. Takaya: Switchable C- and N-Bound Isomers of Transition-Metal Cyanocarbanions: Synthesis and Interconversions of Cyclopentadienyl Ruthenium Complexes of Phenylsulfonylacetonitrile Anions, Chem. Eur. J., 14, 2482-2498(2008).
S.-I. Murahashi, and D. Zhang: Ruthenium Catalyzed Biomimetic Oxidation in Organic Synthesis Inspired by Cytochrome P-450, Chemical Society Reviews, 37, 1490-1501 (2008).
K. Suzuki, T. Watanabe, S.-I. Murahashi: Aerobic Oxidative Transformation of Primary Amines to Oximes Catalyzed by 1,1-Diphenyl-2-picrylhydrazyl (DPPH) and Tungstated Alumina, Angew. Chem. Int. Ed., 47, 2079-2081(2008).
S.-I. Murahashi, Y. Okano, H. Sato, T. Nakae, N. Komiya: Aerobic Ruthenium-Catalyzed Oxidative Transformation of Secondary Amines to Imines, Synlett, 1675-1678 (2007).
L. Provins, and S.-I. Murahashi: Oxidation of Olefins Catalyzed by New Binaphthyl-ruthenium(III) Complexes, Arkivoc, (x)107-120 (2007).
S.-I. Murahashi: Development of Ruthenium Catalyzed Oxidation Reactions Inspired by Cytochrome P-450, J. Synth. Org. Chem. Jpn., 65, 1, 2-13 (2007).
Y. Imada, H. Iida, S. Ono, Y. Masui, S.-I. Murahashi: Flavin-Catalyzed Oxidation of Amines and Sulfides with Molecular Oxygene: Biomimetic Green Oxidation, Chem. Asian. J. 1, 136-147 (2006).
Y. Imada, M. Nishida, K. Kutsuwa, S. I. Murahashi, T. Naota, Palladium-Catalyzed Asymmetric Amination of 2,3-Allyl Phosphates, Org. Lett. 7, 5837-5839(2005).
S.-I. Murahashi, S. Noji, T. Hirabayashi, N. Komiya, Manganese-Catalyzed Enantioselective Oxidation of C-H Bonds of Alkanes and Silyl Ethers to Optically Active Ketones, Tetrahedron Asymmetry 16, 3527-3535(2005).
S.-I. Murahashi, N. Komiya, H. Terai, Ruthenium-Catalyzed Oxidative Cyanation of TertiaryAmines with Hydrogen Peroxide and Sodium Cyanide, Angew. Chem. Int. Ed. 44, 6931-6933(2005).
Y. Imada, H. Iida, S.-I. Murahashi, and T. Naota, An Aerobic Organocatalytic, and Chemoselective Method for Baeyer-Villiger Oxidation, Angew. Chem. Internal. Ed. 44, 1704-1706(2005).
S.-I. Murahashi, S. Noji, and N. Komiya, Catalytic Enantioselective Oxidation of Alkanes and Alkenes Using (Salen)Manganese Complexes Bearing a Chiral Binaphthyl Strapped Unit, Adv. Synth. Catal. 346, 195-198(2004).
H. Terai, H. Takaya, and S.-I. Murahashi,. Iridium-Catalyzed Selective C-C Bond Cleavage of Nitriles and Ketones. Synlett 2185-2187(2004).
S.-I. Murahashi. S. Noji, T. Hirabayashi, and N. Komiya, Manganase-Catalyzed Oxidative Transformation of Silyl Ethers to Ketones: Enantioselective Synthesis of Optically Active β-and γ-Siloxylketones. Synlett. 1739-1742(2004).
Shun-Ichi Murahashi: Transition-Metal-Based Lewis Acid, Base, and Ambiphilic Catalyst. Development of Non-salt Processes, J. Syn. Org. Chem. Jpn., 61, 425-435 (2003).
S.-I. Murahashi, N. Komiya, H. Terai, and T. Nakae, Aerobic Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Sodium Cyanide, J. Am. Chem. Soc. 125, 15312-15313(2003).
Y. Imada, H. Iida, S. Ono, and S.- I. Murahashi, Flavin Catalyzed Oxidations of Sulfides and Amines with Molecular Oxygen, J. Am. Chem. Soc. 125, 2868-2869(2003).
H. Takaya, K. Yoshida, K. Isozaki, H. Terai, and S. - I. Murahashi, Transition-Metal-Based Lewis Acid and Base Ambiphilic Catalysts of Iridium Hydride Complexes: Multicomponent Synthesis of Glutarimides, Angew. Chem. Inter. Ed. 42, 3302-3304(2003).
S. - I. Murahashi, X. Zhou, and N. Komiya, Chlorinated Phthalocyanine Iron(II) Complex Catalyzed Oxidation of Alkanes and Alkenes with Molecular Oxygen in the Presence of Acetaldehyde, Synlett 321-324(2003).
S.-I. Murahashi: Development of Biomimetic Catalytic Oxidation Reactions, Shokubai 44, 259-264 (2002).
S.-I. Murahashi, H. Takaya, and T. Naota: Ruthenium Catalysis in Organic Synthesis, Pure Appl. Chem. 74, 19−23 (2002).
T. Naota, A. Tanna, S. Kamuro, and S.-I. Murahashi: Mechanism of the Interconversions between C- and N-Bound Transition Metal a-Cyanocarbanions, J. Am. Chem. Soc. 124, 6842−6843 (2002).
S.-I. Murahashi, S. Ono, and Y. Imada: Asymmetric Baeyer−Villiger Reaction with Hydrogen Peroxide Catalyzed by a Novel Planar-Chiral Bisflavin, Angew. Chem. Int. Ed. 41, 2366−2368 (2002).
S.-I. Murahashi, Y. Imada, T. Kawakami, K. Harada, Y. Yonemushi, and N. Tomita: Enantioselective Addition of Ketene Silyl Acetals to Nitrones Catalyzed by Chiral Titanium Complexes. Synthesis of Optically Active b-Amino Acids, J. Am. Chem. Soc. 124, 2888−2889 (2002).
S.-I. Murahashi: Palladium-Catalyzed Cross-Coupling Reactions of Organic Halides with Grignard Reagents, Organolithium Compounds, and Heteroatom Nucleophiles, J. Organomet. Chem. 653, 27−33 (2002).
Y. Imada, K. Ueno, K. Kutsuwa, and S.-I. Murahashi: Palladium-Catalyzed Asymmetric Alkylation of Alka-2,3-dienyl Phosphates. Synthesis of Optically Active Allenes, Chem. Lett. 140−141 (2002).
T. Hottop, H.-J. Gutke, and S.-I. Murahashi: Synthesis of 4-Demethoxyadriamycinone Utilizing Ruthenium-Catalyzed Oxidation of Allyl Acetates, Tetrahedron Lett. 42, 3343−3346 (2001).
H. Takaya and S.-I. Murahashi: Activation of C―H Bonds a to Nitriles for Combinatorial Chemistry: Ruthenium-Catalyzed Aldol and Michael Reactions of Polymer-Supported Nitriles, Synlett 991−992 (2001).
S.-I. Murahashi, N. Komiya, Y. Hayashi, and T. Kumano: Copper Complexes for Catalytic, Aerobic Oxidation of Hydrocarbons, Pure & Appl. Chem. 73, 311−314 (2001).
H. Takaya, S. Kojima, and S.-I. Murahashi: Rhodium Complex-Catalyzed Reaction of Isonitriles with Carbonyl Compounds: Catalytic Synthesis of Pyrroles, Org. Lett. 3, 421−424 (2001).
T. Naota, A. Tannna, and S.-I. Murahashi: Carbon-Carbon Bond Forming Reactions of N-Bound Transition Metal a-Cyanocarbanions: A Mechanistic Probe for Catalytic Michael Reactions of Nitriles, Chem. Commun. 63−64 (2001).
N. Komiya, S. Noji, and S.-I. Murahashi: Ruthenium-catalysed Oxidation of Alkanes with Peracetic Acid in Trifluoroacetic Acid: Ruthenium as an Efficient Catalyst for the Oxidation of Unactivated C-H Bonds, Chem. Commun. 65−66 (2001).
S.-I. Murahashi, N. Komiya, Y. Oda, T. Kuwabara, and T. Naota: Ruthenium-Catalyzed Oxidation of Alkanes with tert-Butyl Hydroperoxide and Peracetic Acid, J. Org. Chem. 65, 9186−9193 (2000).
S.-I. Murahashi, A. Mitani, and K. Kitao: Ruthenium Catalyzed Glycine-Selective Oxidative Backbone Modification of Peptides, Tetrahedron Lett. 41, 10246−10249 (2000).
T. Kawakami, H. Ohtake, H. Arakawa, T. Okachi, Y. Imada, and S.-I. Murahashi: Asymmetric Synthesis of b-Amio Acids by Addition of Chiral Enolates to Nitrones via N-Acyloxyiminium Ions, Bull. Chem. Soc. Jpn. 73, 2423−2444 (2000).
S.-I. Murahashi, K. Take, T. Naota, and H. Takaya: Aldol and Michael Reactions of Nitriles Catalyzed by Cyclopentadienylruthenium Enolate Complexes, Synlett 1016−1018 (2000).
S.-I. Murahashi and H. Takaya: Low-Valent Ruthenium and Iridium Hydride Complexes as Alternatives to Lewis Acid and Base Catalysts, Acc. Chem. Res. 33, 225−233 (2000).
T. Naota, A. Tannna, and S.-I. Murahashi: Synthesis and Characterization of C- and N-Bound Isomers of Transition Metal a-Cyanocarbanions, J. Am. Chem. Soc. 122, 2960−2961 (2000).
S.-I. Murahashi, T. Tsuji, and S. Ito: Synthesis of Optically Active N-Hydroxylamines by Asymmetric Hydrogenation of Nitrones with Iridium Catalysts, Chem. Commun. 409−410 (2000).
S.-I. Murahashi, K. Kitao, and A. Mitani: Glycine-Selective Ruthenium Catalyzed Oxidative Modification of Short Peptides, Peptide Science 1999, 137−140 (2000).
S.-I. Murahashi, J. Sun, H. Kurosawa, and Y. Imada: Synthesis of Homochiral b-Sulfinyl Nitrones and Their Application for Enantioselective Synthesis of (+)-Euphococcinine, Heterocycles 52, 557−561 (2000).
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著書・総説 |
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村橋俊一: 私が化学を選んだ理由、化学だいすきクラブニュースレター、日本化学会化学教育協議会、3(2008.夏号).
S.-I. Muranashi, N. Komiya, Ruthenium-catalyzed Oxidation for Organic Synthesis, In Modern Oxidation Methods, 2nd Ed., Ed., J.-E. Backvall, Wiley-VCH, Weinheim, in press.
Shun-Ichi Murahashi: Palladium-Phosphine-Complex-Catalyzed Reaction of Organolithium Compounds and Alkenyl Halides: (Z)-β-[2-(N,N-dimethylamino)phenyl]styrene, In Thematic Collection Organic Synthesis, Ed., R. Danheiser, in press.
Shun-Ichi. Murahashi and Yasushi Imada: Asymmetric Synthesis of Amines and Amino Acids from Amines, Asymmetric Synthesis-The Essentials, Eds., S. Braese, M. Christmann, Wiley-VCH, Weinheim, 40-44 (2007).
Shun-Ichi Murahashi and Changjia Zhao::Pentahydridobis(triisopropylphosphine)iridium(V) In Electronic Encyclopedia of Reagents for Organic Synthesis, Ed. L. A. Paquette, Wiley, New York, (2006).
Shun-Ichi Murahashi and Changjia Zhao: Dichlorotris(triphenylphosphine)ruthenium(II) In Electronic Encyclopedia of Reagents for Organic Synthesis, Ed. L. A. Paquette, Wiley, New York, (2006).
Shun-Ichi. Murahashi: Transition Metal Catalyzed C-H Activation of Pronucleophile by α-Heteroatom Effect, In Handbook of CH Transformation, Ed. G. Dyker, Wiley-VCH, Weinheim,Vol.2, 319-328 (2005).
Shun-Ichi Murahashi: Synthesis of Nitriles with Retention of the Cyano Group, In Science of Synthesis, Ed., Shun-Ichi Murahashi, Thieme, Stuttgart, Vol 19, 345-425 (2004).
Shun-Ichi Murahashi and Yasushi Imada: Amine Oxidations, In Transition Metals for Organic Syntheis, Vol 2. Second Revised and Enlarged, Ed., M. Beller, C. Bolm, Wiley-VCH, Weinheim, 497-507 (2004).
Shun-Ichi Murahashi and Naruyoshi Komiya: Ruthenium-Catalyzed Oxidation of Alkenes, Alcohols, Amines, beta-Lactams, Phenols, and Hydrocarbons, In Modern Oxidation Methods, Ed., J.-E. Backvall, Wiley-VCH, Weinheim, 165-191(2004).
Shun-Ichi Murahashi and Naruyoshi Komiya: Oxidation Reactions, In Ruthenium in Organic Synthesis Ed., Shun-Ichi Murahashi, Wiley-VCH, Weinheim, 53-93 (2004).
S.-I. Murahashi and N. Komiya: Oxidation of Amines, Alcohols, and Related Compounds, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2881−2894 (2002).
T. Hosokawa and S.-I. Murahashi: Oxypalladation−Dehydropalladation Tandem and Related Reactions, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2169−2192 (2002).
T. Hosokawa and S.-I. Murahashi: Intermolecular Oxypalladation Not Accompanied by Dehydrogenation, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2161−2168 (2002).
T. Hosokawa and S.-I. Murahashi: Other Intramolecular Oxypalladation-Dehydropalladation Reactions, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2141−2159 (2002).
S.-I. Murahashi and Y. Imada: Palladium-Catalyzed Substitution Reactions of Nitrogen and Other Group 15 Atom Containing Allylic Derivatives, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 1817−1825 (2002).
S.-I. Murahashi: Recommendation for Green Chemistry, Kagaku to Kyoiku, 50, 426−429 (2002).
S.-I. Murahashi: Green Chemistry−Homogeneous Complex Catalysts, In Green Chemistry−Chemistry for Sustainable Society, Ed., by Makoto Misonou and S.-I. Murahashi, Kodansha, Tokyo, 99−111 (2001).
S.-I. Murahashi: Development of Transition Metal Catalyst as Lewis Acid or Base Substitutes, Organomet. News, 90−93 (2001).
S.-I. Murahashi: Green Chemistry and the Development of New Catalyst Therefor, Kagaku Kogyo, 51, 409−416 (2000).
S.-I. Murahashi: Exploitation of New Catalytic Reactions, Kagaku Kogyo, 51, 52−57 (2000).
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