Okayama University of Science

Last update June 2016

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  Shun-Ichi Murahashi (Professor, Dr.)
 

Contact Address

  Department of Applied Chemistry,
  Okayama University of Science,
  Ridai-cho, Okayama 700-0005, Japan
  Fax +81-86-256-4292
  URL http://www.ous.ac.jp/DAC/otera/murahashi/index.html
   
  Born
  Osaka, Japan; May 12, 1937
  Education
 

Bachelor:

Master:

Ph D.:

Osaka University, 1961

Osaka University, 1963

Osaka University (Prof. Ichiro Moritani), 1967

 
Postdoctoral Fellow:  Columbia University (Prof. Ronald Breslow) , 1968-1970
   
  Academic Positions
 

Assistant Professor, Osaka University, 1963-1972

Associate Professor, Osaka University, 1972-1979

Professor, Osaka University, 1979-2001

Visiting Prof. Universite de Rennes, 1992

Visiting Prof. Institute of Fundamental Research of Organic Chemistry, Kyushu University, 1995-2001

Visiting Prof. Univerite P. M. Curie, Paris, 1997

Councilor, Osaka University, 1998

Emeritus Professor of Osaka University, 2001-

Professor of Okayama University of Science, 2001-2013.3

   
  Field of Research
 

Organometallic Chemistry directed towards Organic Synthesis

Palladium- and Ruthenium-Catalyzed Reaction

C-H Activation

Non-salt Processes, Transition-metal based Acid Base Ambiphilic catalyst

Biomimetic Catalytic Oxidation Reactions

Cytochrome P-450 type Oxidation

Flavin catalyzed Oxidation reaction
   
Award
 

Award for Young Chemists, The Chemical Society of Japan (1970)

JSPS NSERC Lectureship (1991)

The Award of the Chemical Society of Japan (1995)

Docteur Honoris Causa, Universite de Rennes (1995)

MERCK-Schuchardt Lectureship (1996)

Humboldt Research Award (2002)

Bull.Chem. Soc. Award (2002)

Minakata-Avogadro Lecture Award (2003)

Special Award in Synthetic Organic Chemistry Japan (2005)

Japan Academy Prize (2010)

The Order of the Sacred Treasure Gold Rays with Neck-Ribon (2012)

   
 
Chemical Society
  President, The Chemical Society of Japan (2000)
   
  Director, The Kinki Chemical Society, Japan (1985-1997)
  Director, The Chemical Society of Japan (1989-1991)
  Director, The Society of Synthetic Organic Chemistry, Japan (1992-1993)
  Vice President, The Chemical Society of Japan (1994)
  Vice President, The Kinki Chemical Society, Japan (1997-1999)
   
  Government Office
 

The Member of the Science Council of Japan (2000-present)

  The Member of the Committee of the Japan Science and Technology (2002-2007)
 
Chairman, Committee of Research on Chemistry Creating Organic Chemistry with Novel Functions, Japan Society of the Promotion of Science (2003-2007)
   
  Research Program
 
Chairman, Priority Area "Reactive Organometallics" of the Grant-in-Aid for Scientific Research, Ministry of Culture, Education, and Sports (1992-1995)
 
Project Leader, Research for the Future Program "Enviromentally Friendly Catalytic Processes", Japan Society of the Promotion of Science (1996-2001)
   
  Editor
 

Editorial Board, J. Molecular Catalysis, B (1998-2001)

Honorary Advisory Board, Synlett (1992-2009)

The Editor-in-Chief, Chemistry Letters (1994-1998)

Editorial Board, Green Chemistry (1999-2001)

Advisory Board, Chemistry Letters (2005-present)

   
  International Conference
 
IUPAC symposium of Organometallic Chemistry directed towards Organic Synthesis (OMCOS)
  International Advisory Board: (1991-present)
  Chairman: The 7th IUPAC symposium of Organometallic Chemistry directed towards Organic Synthesis (OMCOS-7) (1993, Kobe)
The International Kyoto Conference on Organic Chemistry, Kyoto (IKCOC)
  International Advisory Board:(1979-present)
The International Symposium on Homogeneous Catalysis (ISHC)
  International Advisory Board: (1998-present)
   
  Membership
 

The Chemical Society of Japan (Honorary Member)

Federation of Asian Chemical Societies (FACS) (Honorary Member)

The Society of  Synthetic Organic Chemistry, Japan (Honorary Member)

American Chemical Society

The Royal Society of Chemistry

The Kinki Chemical Society, Japan

 
  Invited and Plenary Lectures at International Symposium
 

Functionalization of sp3C-­-H bonds  with  Transition-­-metal  Catalysts and Organocatalysts The third International Symposium on C-H Activation (ISCHA), Montreal, Canada, 2016.5.30-6.2

The Symposium-Celebrating the 90th Birthday of Lixin Dai, Shanghai, China, 2014.10.10

“Green Catalytic Reactions for Sustainable Development” Frontiers of Organometallic Chemistry (FOC 2012), St. Petersburg, Russia, 2012.9.21-22.

“Biomimetic Catalytic Oxidations with Molecular Oxygen Inspired by Cytochrome P-450 and Flavoenzyme” The 241st ACS National Meeting, Recent Progress in Catalytic and Biomimetic Chemistry (The Breslow Symposium), Anaheim, USA, 2011.3.27.

"Transition-metal catalyzed reactions of carbonyl compounds and trifluoromethylated compounds: A sp3C-H bond activation induced by α heteroatom effect", The International Chemical Congress of Pacific Basin Societies, Hawaii, USA, 2010.12.18.

"Exploitation of Green Catalytic Reactions for Sustainable Development", Takasago Symposium 2010 -New Paradigm Led by Catalysts-, Tokyo Japan, 2010.12.3.

"Green Catalytic Reactions for Sustainable Development", International Conference on Green & Sustainable Chemistry, Singapore, 2009.8.3-5.

"Green Catalytic Reactions for Sustainable Development", 11th International Symposium on Natural Products Chemistry, Karachi, Pakistan, 2008. 10.29-11.1.

"Recent Advances in Green Catalytic Reactions with Transition-metal Catalysts", 15th National Conference on Organometallic Chemistry, Nanjing, China, 2008. 10.20-23.

“Green Catalytic Reactions for Sustainable Development,” 9th International Symposium on Green Chemistry in China, Hefei, China, 2008.5.12-14.

“Green Catalytic Reactions for Sustainable Development,” Farewell Symposium Roger Sheldon A Journey in Green Chemistry, Delft, The Netherlands, 2007. 12. 6-7.

A*STAR-Noyori Forum Joint Symposium, Singapore, 2007. 5. 14-16.

International Symposium on Current Perspectives in Organic Chemistry, Kolkata, India, 2006. 12. 7-9.

The 21th Century COE International Symposium, Nagaoka, Japan, 2006. 9. 29-30.

The 4th Conference on Chemistry, Cairo, Egypt, 2006. 3. 5-8.

Organic Chemistry, Today and Tomorrow, Bangalore, India, 2006. 1. 4-7.

The 2005 Pacifichem Conference, Green Chemical Processes, Hawaii, USA, 2005. 12. 7.

The 15th International Symposium on Fine Chemistry and Functional Polymers, Shanghai, China, 2005. 10. 17-20.

The 7th World Congress on Recovery, Recycle, Re-integration, Chinese Academy of Science, Beijing, China, 2005. 9. 25-29.

The 1st International Symposium on Organic Electron Transfer Chemistry directed toward Organic Synthesis, Osaka, Japan, 2005. 3. 19-22.

2nd Symposium of High-tech Research Center Okayama University of Science, 2003. 11.24-25.

Minakata-Avogadro Lectureship, University of Rome, 2003. 4. 28-5.5. Rome, Bari, Bologna, Milano, Italy.

The lectureship to the memory of Ta-shue Chou, Taipei, Taiwan, 2003. 2. 22.

The 11th Japan–Korea Seminar on Organic Chemistry, Teju, Korea, 2002.11.7–10.

The 13th International Symposium on Homogeneous Catalysis, Tarragona, Spain, 2002.9.3–7.

India–Japan NOST Symposim on Organic Chemistry, Trivandrum, India, 2001.12.13–15.

First Japan–Australia Symposium on Organic Chemistry (JASOC-1), Melbourne, Australia, 2001.12.10–11.

First NIAF MeRinOS Joint Meeting on Fundamental and Applied Aspect of Synthesis, Belgium, 2001.9.28–10.2.

18th International Congress of Heterocyclic Chemistry, Yokohama, Japan, 2001.7.29–8.3.

Post OMCOS-XI Symposium, Thirty Years of The Cross-Coupling reaction, Kyoto, Japan, 2001.7.27–28.

11th IUPAC Symposium on Organometallic Chemistry directed towards Organic Synthesis, Taipei, Taiwan, 2001.7.22–26.

The 87th Annual Meeting of the Korean Chemical Society, Seoul, Korea, 2001.4.20.

The Breslow Symposium—Celebrating the 70th Birthday of Ronald Breslow, New York, USA, 2001.3.24.

2000 International Chemical Congress of Pacific Basin Societies (Pacifichem 2000), Honolulu, Hawaii, USA, 2000.12.14–19.

The 10th Japan–Korea Seminar on Organic Chemistry, Sendai, Japan, 2000.11.26–28.

2000 International Symposium on Organic Reactions (ISOR 2000), Kyoto, Japan, 2000.10.24.

Special Symposium Inaugurating the Herbert C. Brown Distinguished Professorship and the Annual Industrial Associates Meeting, West Lafyete, USA, 2000.9.28–30.

Congrés de la Société Française de Chimie, Rennes, France, 2000.9.18–22.

XIXth International Conference on Organometallic Chemistry (ICOMC), Shanghai, China, 2000.7.23–28.

Gratama Workshop 2000-Chemistry and Chemical Technology for a Sustainable Society, Osaka, Japan, 2000.4.21–25.

 
  Publications
 
   
 
Recent Original Papers
 

H. Iida, Y. Imada, and S.-I. Murahashi:  Biomimetic Flavin-catalyzed Reactions for Organic Symthesis:  Org. Bio. Chem., 13, 7599-7613 (2015).

S.-I. Murahashi, D. Zhang, H. Iida, T. Miyawaki, M. Uenaka, K. Murano, and K. Meguro: Flavin-catalyzed aerobic oxidation of sulfides and thiols with formic acid/trimethylamine, Chem. Commun., 10295-10298 (2014).

Q. Wang, F. Huan, H. Shen, J-C. Xiao, M. Gao, X. Yang, S.-I. Murahashi, Q-Y. Chen, and Y. Guo:  Organocatalytic Reactions of a-Trifluorometylated Esters with Terminal Alkenes at Room Temperature, J. Org. Chem., 78, 12525-12553 (2013).

Y. Hayashi, N. Komiya, K. Suzuki, and S.-I. Murahashi:  Copper-catalyzed aerobic Oxidative Functionalization of C-H Bonds of Alkanes in the presence of Acetaldehyde under mild conditions, Tetrahedron Lett., 54, 2706-2709 (2013).

K. Suzuki, T. Watanabe, and S.-I. Murahashi: Oxidation of Primary Amines to Oximes with Molecular Oxygen using 1,1-Diphenyl-2-picrylhydrazyl and WO3/Al2O3 as Catalysts, J. Org. Chem., 78, 2301-2310 (2013).

S.-I. Murahashi, N. Miyaguchi, S. Noda, T. Naota, A. Fujii, Y. Inubushi and N. Komiya: Ruthenium-Catalyzed Oxidative Dearomatization of Phenols to 4-(tert-Butylperoxy)cyclohexadienones: Synthesis of 2-Substituted Quinones from p-Substituted Phenols, Eur. J. Org. Chem, 27, 5355-5365 (2011).

S.-I. Murahash, Development of biomimetic catalytic oxidation methods and non-salt methods using transition metal-based acid and base ambiphilic catalysts, Proc. Jpn. Acad. Ser. B, 87, 242-253 (2011)

S.-I. Murahashi, A. Fujii, Y. Inubushi and N. Komiya: Synthesis of 2-substituted quinones, vitamin K3, and vitamin K1 from p-cresol. BF3·OEt2-catalyzed methyl migration of 4-tert-butyldioxycyclohexadienones, Tetrahedron Letters, 51, 2339-2341 (2010).

H. Takaya, M. Ito, and S.-I. Murahashi: Rhenium-Catalyzed Addition of Carbonyl Compounds to the Carbon-Nitrogen Triple Bonds of Nitriles:α-C-H Activation of Carbonyl Compounds, J. Am.Chem. Soc.,131,10824-10825 (2009).

S.-I. Murahashi, T. Naota, and Y. Nakano: Ruthenium-Catalyzed Regioselective Reactions of Nitriles and 1,3−Dicarbonyl Compounds with Terminal Alkynes, Synlett, 3355-3359 (2009).

Y. Guo, X. Zhao, D. Zhang, S.-I. Murahashi: Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes:A Csp3---H Bond Activation a to the Trifluoromethyl Group, Angew. Chem. Int. Ed. 48, 2047-2049 (2009).

S.-I. Murahashi, T. Nakae, H. Terai, N. Komiya:  Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Molecular Oxygen or Hydrogen Peroxide and Sodium Cyanide: sp3 C-H Bond Activation and Carbon-Carbon Bond Formation, J. Am. Chem. Soc. 130, 11005-11012 (2008).

T. Naota, A. Tanna, S. Kamuro, M. Hieda, K. Ogata, S.-I. Murahashi, H. Takaya:  Switchable C- and N-Bound Isomers of Transition-Metal Cyanocarbanions: Synthesis and Interconversions of Cyclopentadienyl Ruthenium Complexes of Phenylsulfonylacetonitrile Anions, Chem. Eur. J. 14, 2482-2498(2008).

S.-I. Murahashi, and D. Zhang:  Ruthenium Catalyzed Biomimetic Oxidation in Organic Synthesis Inspired by Cytochrome P-450, Chemical Society Reviews 37, 1490-1501 (2008).

K. Suzuki, T. Watanabe, S.-I. Murahashi:  Aerobic Oxidation of Primary Amines to Oximes Catalyzed by DPPH and WO3/Al2O3, Angew. Chem. Int. Ed. 47, 2079-2081(2008).

S.-I. Murahashi, Y. Okano, H. Sato, T. Nakae, N. Komiya: Aerobic Ruthenium-Catalyzed Oxidative Transformation of Secondary Amines to Imines, Synlett, 1675-1678 (2007).

L. Provins, and S.-I. Murahashi:  Oxidation of Olefins Catalyzed by New Binaphthyl-ruthenium(III) Complexes, Arkivoc (x)107-120 (2007).

S.-I. Murahashi:  Development of Ruthenium Catalyzed Oxidation Reactions Inspired by Cytochrome P-450, J. Synth. Org. Chem. Jpn.65, 1, 2-13 (2007).

Y. Imada, H. Iida, S. Ono, Y. Masui, S.-I. Murahashi:  Flavin-Catalyzed Oxidation of Amines and Sulfides with Molecular Oxygene: Biomimetic Green Oxidation, Chem. Asian. J. 1, 136-147 (2006).

Y. Imada, M. Nishida, K. Kutsuwa, S.-I. Murahashi, T. Naota: Palladium-Catalyzed Asymmetric Amination of 2,3-Allyl Phosphates, Org. Lett. 7, 5837-5839 (2005).

S.-I. Murahashi, S. Noji, T. Hirabayashi, N. Komiya: Manganese-Catalyzed Enantioselective Oxidation of C-H Bonds of Alkanes and Silyl Ethers to Optically Active Ketones, Tetrahedron Asymmetry 16, 3527-3535 (2005).

S.-I. Murahashi, N. Komiya, H. Terai:  Ruthenium-Catalyzed Oxidative Cyanation of TertiaryAmines with Hydrogen Peroxide and Sodium Cyanide, Angew. Chem. Int. Ed. 44, 6931-6933 (2005).

Y. Imada, H. Iida, S.-I. Murahashi, T. Naota: An Aerobic Organocatalytic, and Chemoselective Method for Baeyer-Villiger Oxidation, Angew. Chem. Internal. Ed. 44, 1704-1706 (2005).

S.-I. Murahashi, S. Noji, and N. Komiya: Catalytic Enantioselective Oxidation of Alkanes and Alkenes Using (Salen)Manganese Complexes Bearing a Chiral Binaphthyl Strapped Unit,  Adv. Synth. Catal. 346, 195-198 (2004).

H. Terai, H. Takaya, S.-I. Murahashi: Iridium-Catalyzed Selective C-C Bond Cleavage of Nitriles and Ketones. Synlett 2185-2187 (2004).

 

S.-I. Murahashi. S. Noji, T. Hirabayashi, N. Komiya: Manganase-Catalyzed Oxidative Transformation of Silyl Ethers to Ketones: Enantioselective Synthesis of Optically Active β-and γ-Siloxylketones. Synlett 1739-174 2(2004).

S.-I. Murahashi:  Transition-Metal-Based Lewis Acid, Base, and Ambiphilic Catalyst. Development of Non-salt Processes, J. Syn. Org. Chem. Jpn, 61, 425-435 (2003).

S.-I. Murahashi, N. Komiya, H. Terai, T. Nakae: Aerobic Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Sodium Cyanide,  J. Am. Chem. Soc. 125, 15312-15313 (2003).

Y. Imada, H. Iida, S. Ono, S.- I. Murahashi: Flavin Catalyzed Oxidations of Sulfides and Amines with Molecular Oxygen, J. Am. Chem. Soc. 125, 2868-2869 (2003).

H. Takaya, K. Yoshida, K. Isozaki, H. Terai, S. - I. Murahashi: Transition-Metal-Based Lewis Acid and Base Ambiphilic Catalysts of Iridium Hydride Complexes: Multicomponent Synthesis of Glutarimides, Angew. Chem. Inter. Ed. 42, 3302-3304 (2003).

S. - I. Murahashi, X. Zhou, N. Komiya: Chlorinated Phthalocyanine Iron(II) Complex Catalyzed Oxidation of Alkanes and Alkenes with Molecular Oxygen in the Presence of Acetaldehyde, Synlett 321-324(2003).

S.-I. Murahashi: Development of Biomimetic Catalytic Oxidation Reactions, Shokubai44, 259-264 (2002).

S.-I. Murahashi, H. Takaya, T. Naota: Ruthenium Catalysis in Organic Synthesis, Pure Appl. Chem. 74, 19-23 (2002).

T. Naota, A. Tannna, S. Kamuro, S.-I. Murahashi: Mechanism of the Interconversions between C- and N-Bound Transition Metal α-Cyanocarbanions, J. Am. Chem. Soc. 124, 6842-6843 (2002).

S.-I. Murahashi, S. Ono, Y. Imada: Asymmetric Baeyer-Villiger Reaction with Hydrogen Peroxide Catalyzed by a Novel Planar-Chiral Bisflavin, Angew, Chem., Int. Ed. 41, 2366-2368 (2002).

S.-I. Murahashi, Y.Imada, T. Kawakami, K. Harada, Y. Yonemushi, and N. Tomita, Enantioselective Addition of Ketene Silyl Acetals to Nitrones Catalyzed by Chiral Titanium Complexes.  Synthesis of Optically Active β-Amino Acids, J. Am. Chem. Soc. 124, 2888-2889 (2002).

S.-I. Murahashi:  Palladium-Catalyzed Cross-Coupling Reactions of Organic Halides with Grignard Reagents, Organolithium Compounds, and Heteroatom Nucleophiles, J. Organomet. Chem. 653, 27-33 (2002).

Y. Imada, K.Ueno, K. Kutsuwa, S.-I. Murahashi: Palladium-Catalyzed Asymmetric Alkylation of Alka-2,3-dienyl Phosphates. Synthesis of Optically Active Allenes, Chem. Lett. 140-141 (2002). 

T. Hottop, H.-J. Gutke, and S.-I. Murahashi: Synthesis of 4-Demethoxyadriamycinone Utilizing Ruthenium-Catalyzed Oxidation of Allyl Acetates, Tetrahedron Lett., 42, 3343–3346 (2001).

H. Takaya and S.-I. Murahashi: Activation of C—H Bonds α to Nitriles for Combinatorial Chemistry: Ruthenium-Catalyzed Aldol and Michael Reactions of Polymer-Supported Nitriles, Synlett, 991–992 (2001).

S.-I. Murahashi, N. Komiya, Y. Hayashi, and T. Kumano: Copper Complexes for Catalytic, Aerobic Oxidation of Hydrocarbons, Pure & Appl. Chem., 73, 311–314 (2001).

H. Takaya, S. Kojima, and S.-I. Murahashi: Rhodium Complex-Catalyzed Reaction of Isonitriles with Carbonyl Compounds: Catalytic Synthesis of Pyrroles, Org. Lett., 3, 421–424 (2001).

T. Naota, A. Tannna, and S.-I. Murahashi: Carbon-Carbon Bond Forming Reactions of N-Bound Transition Metal α-Cyanocarbanions: A Mechanistic Probe for Catalytic Michael Reactions of Nitriles, Chem. Commun., 63–64 (2001).

N. Komiya, S. Noji, and S.-I. Murahashi: Ruthenium-catalysed Oxidation of Alkanes with Peracetic Acid in Trifluoroacetic Acid: Ruthenium as an Efficient Catalyst for the Oxidation of Unactivated C-H Bonds, Chem. Commun., 65–66 (2001).

S.-I. Murahashi, N. Komiya, Y. Oda, T. Kuwabara, and T. Naota: Ruthenium-Catalyzed Oxidation of Alkanes with tert-Butyl Hydroperoxide and Peracetic Acid, J. Org. Chem., 65, 9186–9193 (2000).

S.-I. Murahashi, A. Mitani, and K. Kitao: Ruthenium Catalyzed Glycine-Selective Oxidative Backbone Modification of Peptides, Tetrahedron Lett., 41, 10246–10249 (2000).

T. Kawakami, H. Ohtake, H. Arakawa, T. Okachi, Y. Imada, and S.-I. Murahashi: Asymmetric Synthesis of β-Amio Acids by Addition of Chiral Enolates to Nitrones via N-Acyloxyiminium Ions, Bull. Chem. Soc. Jpn., 73, 2423–2444 (2000).

S.-I. Murahashi, K. Take, T. Naota, and H. Takaya: Aldol and Michael Reactions of Nitriles Catalyzed by Cyclopentadienylruthenium Enolate Complexes, Synlett, 1016–1018 (2000).

S.-I. Murahashi and H. Takaya: Low-Valent Ruthenium and Iridium Hydride Complexes as Alternatives to Lewis Acid and Base Catalysts, Acc. Chem. Res., 33, 225–233 (2000).

T. Naota, A. Tannna, and S.-I. Murahashi: Synthesis and Characterization of C- and N-Bound Isomers of Transition Metal α-Cyanocarbanions, J. Am. Chem. Soc., 122, 2960–2961 (2000).

S.-I. Murahashi, T. Tsuji, and S. Ito: Synthesis of Optically Active N-Hydroxylamines by Asymmetric Hydrogenation of Nitrones with Iridium Catalysts, Chem. Commun., 409–410 (2000).

S.-I. Murahashi, K. Kitao, and A. Mitani: Glycine-Selective Ruthenium Catalyzed Oxidative Modification of Short Peptides, Peptide Science 1999, 137–140 (2000).

S.-I. Murahashi, J. Sun, H. Kurosawa, and Y. Imada: Synthesis of Homochiral β-Sulfinyl Nitrones and Their Application for Enantioselective Synthesis of (+)-Euphococcinine, Heterocycles, 52, 557–561 (2000).

 
 
Recent Books and Reviews
 
 

S-I. Murahashi and K. Suzuki: 2,2-Diphenyl-1-(2,4,6-trinitrophenyl) hydrazyl. In Electronic Encyclopedia of Reagents for Organic Synthesis, Ed. David Crich, Wiley, New York, (2012).

S.-I. Murahashi: Pentahydridobis(isopropylphosphine)iridium(V), In Electronic Encyclopedia of Reagents for Organic Synthesis, Ed., L. A. Paquette, Wiley, New York, (2010).

S.-I Murahashi: Dichlorotris(triphenylphosphine)ruthenium(II), In Electronic Encyclopedia of Reagents for Organic Synthesis, Ed., L. A. Paquette, Wiley, New York, (2010).

S.-I. Muranashi, N. Komiya: Ruthenium-catalyzed Oxidation for Organic Synthesis, In Modern Oxidation Methods, 2nd Ed., Ed., J.-E. Backvall, Wiley-VCH, Weinheim, 241-276 (2010).

S.-I. Murahashi and Y. Imada:  Asymmetric Synthesis of Amines and Amino Acids from Amines, Asymmetric Synthesis-The Essentials, Eds., S. Braese, M. Christmann, Wiley-VCH, Weinheim, 40-44 (2007).

S.-I. Murahashi:  Transition Metal Catalyzed C-H Activation of Pronucleophile by α-Heteroatom Effect, In Handbook of CH Transformation, Ed. G. Dyker, Wiley-VCH, Weinheim,Vol.2, 319-328 (2005).

S.-I. Murahashi:  Synthesis of Nitriles with Retention of the Cyano Group, In  Science of  Synthesis, Ed., S.-I. Murahashi, Thieme, Stuttgart, Vol 19, 345-425 (2004).

S.-I. Murahashi and Y. Imada:  Amine Oxidations, In Transition Metals for Organic Syntheis, Vol 2. Second Revised and Enlarged, Ed., M. Beller, C. Bolm, Wiley-VCH, Weinheim, 497-507 (2004).

S.-I. Murahashi and N. Komiya:  Ruthenium-Catalyzed Oxidation of Alkenes, Alcohols, Amines, beta-Lactams, Phenols, and Hydrocarbons, In Modern Oxidation Methods, Ed., J.-E. Backvall, Wiley-VCH, Weinheim, 165-191(2004).

S.-I. Murahashi and N. Komiya:  Oxidation Reactions, In Ruthenium in Organic Synthesis Ed., S.-I. Murahashi, Wiley-VCH, Weinheim, 53-93 (2004).

S.-I. Murahashi and N. Komiya:  Oxidation of Amines, Alcohols, and Related Compounds, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2881–2894 (2002).

T. Hosokawa and S.-I. Murahashi:  Oxypalladation–Dehydropalladation Tandem and Related Reactions, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2169–2192 (2002).

T. Hosokawa and S.-I. Murahashi:  Intermolecular Oxypalladation Not Accompanied by Dehydrogenation, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2161–2168 (2002).

T. Hosokawa and S.-I. Murahashi:  Other Intramolecular Oxypalladation-Dehydropalladation Reactions, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 2141–2159 (2002).

S.-I. Murahashi and Y. Imada:  Palladium-Catalyzed Substitution Reactions of Nitrogen and Other Group 15 Atom Containing Allylic Derivatives, In Handbook of Organopalladium Chemistry for Organic Synthesis, Ed., E. Negishi, John Wiley & Sons, New York, Vol.2, 1817–1825 (2002).

S.-I. Murahashi:  Recommendation for Green Chemistry, Kagaku to Kyoiku, 50, 426–429 (2002).

S.-I. Murahashi: Green Chemistry–Homogeneous Complex Catalysts, In Green Chemistry–Chemistry for Sustainable Society, Ed., by Makoto Misonou and S.-I. Murahashi, Kodansha, Tokyo, 99–111 (2001).

S.-I. Murahashi: Development of Transition Metal Catalyst as Lewis Acid or Base Substitutes, Organomet. News, 90–93 (2001).

S.-I. Murahashi: Green Chemistry and the Development of New Catalyst Therefor, Kagaku Kogyo, 51, 409–416 (2000).

S.-I. Murahashi: Exploitation of New Catalytic Reactions, Kagaku Kogyo, 51, 52–57 (2000).

 
 

 

Last Update 2013.3.21


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